Product ID:06 13F12L MZ7 RESIST GTI, 06-013F12L
MSDS Date:10/08/1996
FSC:8010
NIIN:00N083676
MSDS Number: CGRCT

VALSPAR CORP

1101 THIRD ST SOUTH
MINNEAPOLIS, MN 55415
US

Emergency Phone: 800-228-5635

Info Phone: 612-332-7371

Cage: 13374

VALSPAR CORP

MINNEAPOLIS, MN 55415 US

Telephone: 612-332-7371

Cage: 91346

SILICIC ACID, TETRAETHYL ESTER, HYDROLYZED; (HYDROLYZED

CAS: 68412-37-3

Fraction By Weight: 40%

OSHA PEL N/K

ACGIH TLV: N/K

2-PROPANOL, 1-METHOXY-; (PROPYLENE GLYCOL MONOMETHYL ETHER)

CAS: 107-98-2

RTECS: UB7700000

Fraction By Weight: 15%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 STEL

ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 5-10%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM

2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 1-10%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM/300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 20.0%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

SILICATE, MICA; (MICA)

CAS: 12001-26-2

RTECS: VV8760000

Fraction By Weight: 5%

OSHA PEL 20 MPPCF; Z-3

ACGIH TLV: 3 MG/M3 RDUST

SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <1%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.1 MG/M3 RDUST

SILICA, CRYSTALLINE - CRISTOBALITE; (SILICA)

CAS: 14464-46-1

RTECS: VV7325000

Fraction By Weight: <1%

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 0.05 MG/M3 RDUST

ETHYL BENZENE (SARA 313)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <1%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2.84 LBS/GALLON.

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY

RTECS: 9999999ZZ

CNTNS INGREDS WHICH MAY CAUSE LIVER DMG, KIDNEY

RTECS: 9999999ZZ

KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER.

RTECS: 9999999ZZ

ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD,

RTECS: 9999999ZZ

MONOBUTYL ETHER (EGBE). (EXTRACTED FROM DHHS (NIOSH

RTECS: 9999999ZZ

NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS

RTECS: 9999999ZZ

WELD ON OR NEAR CONTAINER. ALL LABEL WARNINGS

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAN BE ABSORBED THRU SKIN.
HARMFUL IF INHALED. MAY AFFECT BRAIN, NERV SYS/RESP SYS, CAUSING
DIZZ, HDCH, NAUS/RESP IRRIT. CNTNS INGREDS WHICH ARE CORR. OVEREXP
TO INGREDS IN THIS PROD MAY CAUSE NOSE & THROAT IRRIT, EYE IRRIT,
EYE BURNS, SKIN IRRIT, SKIN BURNS, RESP TRACT IRRIT. CHRONIC:
CONTAINS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CRYSTALLINE SILICA-QUARTZ & CRYSTALLINE
SILICA-CRISTOBALITE: IARC MONO, VOL 68, 1997: GROUP 1. NTP 7TH
ANNUAL (SUPDAT)
Effects of Overexposure:HLTH HAZ: GLYCOL ETHER WHICH HAS BEEN SHOWN TO
CAUSE BLOOD EFTS DMG IN LAB ANIMALS. CNTNS CRYSTALLINE SILICA THAT
IARC HAS CONCLUDED MAY CAUSE CANCER IN ANIMALS BUT LIMITED EVIDENCE
OF CANCER IN HUMAN S. RISK OF CANCER DEPENDS ON DURATION &LEVEL OF
EXPOS. IN COATINGS PRODS, RISK IS DUE PRIMARILY TO INHAL OF
(SUPDAT)
Medical Cond Aggravated by Exposure:ANY RESPIRATORY OR SKIN CONDITION.

First Aid:EYE: FLUSH IMMED W/PLENTY OF WATER FOR @ LST 15 MINS & GET
MED ATTN. SKIN: WASH THORO W/SOAP & WATER. CLTHG: REMOVE CONTAMD
CLTHG & SHOES. WASH CLTHG BEFORE REUSE. THORO CLEAN CONTAMD SHOES.
INHAL: RE MOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG
IS DFCLT, GIVE OXYG. GET MED ATTN IMMED. INGEST: DO NOT INDUCE
VOMIT. GIVE LG QTYS OF WATER. IF AVAIL, GIVE SEVERAL GLASSES OF
MILK. (ING 17)

Flash Point Method:TCC
Flash Point:69.0F,20.6C
Lower Limits:1.00%
Upper Limits:19.00%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, AND/OR WATER
FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . CONTAINERS EXPOSED TO FIRE SHOULD BE KEPT COOL WITH
WATER SPRAY.
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:VENTILATE AREA. AVOID BREATHING OF VAPORS. USE
NIOSH APPRVD SCBA OR AIRMASK FOR LARGE SPILLS IN CONFINED AREA.
ELIMINATE IGNITION SOURCES. REMOVE W/INERT ABSORBENT & NON-SPARKING
TOOLS. AVOID CONTACT WITH EYES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CNTNRS SHOULD BE GROUNDED/BONDED WHEN
POURING. AVOID FREE FALL OF LIQ IN EXCESS OF FEW INCHES. KEEP AWAY
FROM HEAT, SPARKS & OPEN FLAME.
Other Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT STORE >120F.
BASED ON PROD FLASH POINT & VAP PRESS SUITABLE STOR SHOULD BE
PROVIDED I/A/W OSHA REG 1910.106. EMPTY CNTNRS MAY CNTN PROD
RESIDUE, INCL FLAM/EXPLO VAPS. DO NOT CUT, PUNCTURE/ (ING 18)

Respiratory Protection:UNLESS AIR MONITORING DEMONSTRATES VAP/MIST
LEVELS ABOVE APPLIC LIMITS, NO RESP IS REQD. IF RESP IS REQD,
APPROP, PROPERLY FITTED RESPIRATOR (NIOSH APPRVD) SHOULD BE WORN
DURING APPLICATION. FOLLOW RE SP MFRS DIRECTIONS FOR RESPIRATOR
USE.
Ventilation:REQD FOR SPRAYING/IN A CONFINED AREA, VENT EQUIP SHOULD BE
EXPLOSION PROOF. ELIMINATE IGNITION SOURCES.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 19)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . USUAL
CLOTHING FOR PAINTING OPERATIONS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN: RPT ON CARCIN, 1994: ANTIC TO BE CARCIN. EFTS OF
OVEREXP: SANDING DUST. PRLNGD EXPOS TO RESPIRABLE CRYSTALLINE
QUARTZ (SILICA) MAY CAUSE DELAYED (CHRONIC) LUNG INJURY
(SILICOSIS). PR LNGD EXPOS OVER TLV MAY PRDCE PNEUMOCONIOSIS.
NOTICE: RPTS HAVE ASSOC RPTD & PRLNGD OCCUP OVEREXP TO SOLVS (ING
12)

Boiling Pt:B.P. Text:156F,69C
Vapor Pres:78 @ 68F
Vapor Density:4.1
Spec Gravity:1.10
Evaporation Rate & Reference:5.6 (BUTYL ACETATE =1)
Solubility in Water:NO
Appearance and Odor:NORMAL FOR A COATINGS PRODUCT.
Percent Volatiles by Volume:41.18

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:SILICON DIOXIDE, CARBON
DIOXIDE/MONOXIDE, METAL OXIDES.

Waste Disposal Methods:DISPOSE IN CHEMICAL DISPOSAL AREA OR IN A MANNER
THAT COMPLIES WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT
INCINERATE CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.